GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 1/6

 

MATERIAL SAFETY DATA SHEET

 

 

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

1.1 Product identifier

Product name:

Para Toluene Sulphonyl Chloride

CAS-No.

98-59-9

EC-No.

202-684-8

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Safety Data Services

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

1.4 Emergency telephone number

022.2820.1198 (1100 hrs GMT to 1900 hrs GMT)

 

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Skin irritation (Category 2)

Serious eye damage (Category 1)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Irritating to skin. Risk of serious damage to eyes.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Hazard pictograms

Signal word :

Danger

Hazard statements

 

H315

Causes skin irritation.

H318

Causes serious eye damage.

Precautionary statements

P280

Wear protective gloves/ eye protection/ face protection.

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove

 

contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard Statements

none

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

 

R38

Irritating to skin.

R41

Risk of serious damage to eyes.

S-phrase(s)

 

S26

In case of contact with eyes, rinse immediately with plenty of water and

 

seek medical advice.

S39

Wear eye/face protection.

2.3 Other hazards

None.

 

 


 

GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 2/6

 

MATERIAL SAFETY DATA SHEET

 

Para Toluene Sulphonyl Chloride

SECTION 3: Composition/information on ingredients

3.1 Substances

 

Formula

C7H7ClO2S

Molecular Weight

190,65 g/mol

Component

Concentration

Para Toluene Sulphonyl Chloride

 

CAS-No. 98-59-9

---

EC-No. 202-684-8

 

 

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough,

wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Blistering, Lachrymation, Material is

extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the

best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

4.3 Indication of any immediate medical attention and special treatment needed

no data available

 
SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides, Sulphur oxides, Hydrogen chloride gas

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable

and/or explosive hydrogen gas.

 

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed

containers for disposal

6.4 Reference to other sections

For disposal see section 13.

 


 

GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 3/6

 

MATERIAL SAFETY DATA SHEET

 

Para Toluene Sulphonyl Chloride

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.

7.2 Conditions for safe storage, including any incompatibilities

Store under inert gas. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Store under inert gas. Moisture sensitive.

7.3 Specific end uses

no data available

 

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Components with workplace control parameters

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

 


 

GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 4/6

 

MATERIAL SAFETY DATA SHEET

 

Para Toluene Sulphonyl Chloride

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Form: crystalline

 

Colour: colourless

Odour

Not available.

Odour threshold

Not available.

pH

Not available.

Melting point/freezing point

Melting point/range: 65 - 69 C - lit.

Initial boiling point and boiling range

128 C - closed cup

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not available.

Upper/lower flammability or explosive limits

Not available.

Vapour pressure

1 hPa at 88 C

Vapour density

Not available.

Relative density

1,400 g/cm3

Water solubility

insoluble

Partition coefficient: n-octanol/water

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Explosive properties

Not available.

Oxidising properties

Not available.

9.2 Other safety information

no data available

 

SECTION 10: Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

no data available

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid :

Exposure to moisture.

10.5 Incompatible materials

Strong oxidizing agents, Strong bases

10.6 Hazardous decomposition products

Other decomposition products - no data available


 

GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 5/6

 

MATERIAL SAFETY DATA SHEET

 

Para Toluene Sulphonyl Chloride

SECTION 11: Toxicological information

 

11.1 Information on toxicological effects

 

Acute toxicity

 

LD50 Oral - rat - 4.680 mg/kg

 

Skin corrosion/irritation

 

no data available

 

Serious eye damage/eye irritation

 

no data available

 

Respiratory or skin sensitization

 

no data available

 

Germ cell mutagenicity

 

no data available

 

Carcinogenicity

 

Carcinogenicity -

 

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

 

Reproductive toxicity

 

no data available

 

Specific target organ toxicity - single exposure

 

no data available

 

Specific target organ toxicity - repeated exposure

 

no data available

 

Aspiration hazard

 

no data available

 

Potential health effects

 

Inhalation

May be harmful if inhaled. Causes respiratory tract irritation.

Ingestion

May be harmful if swallowed.

Skin

May be harmful if absorbed through skin. Causes skin irritation.

Eyes

Causes eye burns.

Signs and Symptoms of Exposure

 

spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough,

 

wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Blistering, Lachrymation, Material is

 

extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the

 

best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

 

investigated.

 

Additional Information

 

RTECS: DB8929000

 

 

SECTION 12: Ecological information

12.1 Toxicity

Toxicity to fish LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h

12.2 Persistence and degradability

Not available.

12.3 Bioaccumulative potential

Not available.

12.4 Mobility in soil

Not available.

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other adverse effects

No data available


 

GarudaBW

15/605-606 mayuresh c.h.s., majaswadi mhada colony, off mahakali caves road, andheri (east), mumbai-400 093.

tel.: 022.2820.1198 28215596

fax.: 022.2820.1201

email.: gcsales@garudachem.com

 

Page 6/6

 

MATERIAL SAFETY DATA SHEET

 

Para Toluene Sulphonyl Chloride

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material

with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

 

SECTION 14: Transport information

14.1 UN number

ADR/RID: - 3261 IMDG: - 3261 IATA: 3261

14.2 UN proper shipping name

ADR/RID: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Tosyl chloride)

IMDG: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Tosyl chloride)

IATA: Corrosive solid, acidic, organic, n.o.s. (Tosyl chloride)

14.3 Transport hazard class(es)

ADR/RID: 8 IMDG: - 8 IATA: - 8

14.4 Packaging group

ADR/RID: - III IMDG: - III IATA: - III

14.5 Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user

no data available

 

SECTION 15: Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

15.2 Chemical Safety Assessment

no data available

 

SECTION 16: Other information

Notice to reader

The statements contained herein are based upon technical data that Garuda Chemicals believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment.

 

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